Blanca is a very passionate and supportive woman. She is shown to love baking and Olaball as much as her husband Roberto. However, she is more accepting of her son's choice of carrer and and more understanding of Gabe's need to be his own man than Roberto as shown when she nodded to her son's words to her husband in the aftermath of the Olaball game.
Blanca first appeared in "Olaball" in her husbands bakery baking empanadas for the Peace festival. She happily greets her son when he enters the bakery. She grows concerned as her husband and son somewhat had a spat. When Gabe turned to leave, Blanca goes after him. Gabe tells her "I wish just once I could make him happy." Blanca tells him she understands and tells him "You make me happy Mijo." At the Olaball games, she hands out the empandas as a concessioner. She is overjoyed when Gabe scores the winning point and when Roberto accepts her son's decision to stay in the Royal Guard after he rescues Isabel and Caterina.
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|Royal Family||Princess Elena • Princess Isabel • Francisco Flores • Luisa Flores • Chancellor Esteban • King Raul and Queen Lucia|
|Royal Staff||Mateo • Gabe • Naomi Turner • Armando • Higgins • Alacazar|
|Villagers of Avalor||Rafa • Daniel Turner • Scarlett Turner • Dona Paloma • Professor Mendoza • Julio • Carmen • Roberto Núñez • Blanca Núñez • Señorita Marisol • Quique • Amara • Sir Cassius • Olivia|
|Other Royalties||King Toshi • King Joaquín • Princess Caterina • King Raja • King Lars • King Hector • King Juan Ramón • Prince Alonso|
|Jaquins||Migs, Luna, and Skylar • Chief Zephyr • Nico • Ciela • Avión • King Verago|
|Spirits||Zuzo • Doña Angelica • Cacahuate • Bobo • Quita Moz|
|Creatures||Jaquins • Chanul • Noblins • Charoca • Yacalli|
|Antagonists||Shuriki • Fiero • Orizaba • Troyo • Lord Elrod • Victor Delgado • Carla Delgado • Marimonda|
|Outside Avalor||Antonio Agama|
|Sofia the First||Sofia the First • Princess Amber • Prince James • King Roland II • Queen Miranda|